The border is in remote area, although there might be some ATMs at the border town in China side, I wouldn't count on withdrawing cash there, and paying visa fee by card is out of question.
To be in the safe side, I would withdraw cash somewhere (in big town where you have more options) in advance.
Points to remember, visa fee is best paid it US dollar. And you should have small notes enough for the visa fee so that you don't run into hassle where the official doesn't have change.
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I need to know, can I pass the border between Nong Khai and Vientiane if my passport expires in 3 months? But I have the certificate from the Russian Consulate